Red luminescent polymeric cuprous organosulfide generated by solvothermal redox reaction
Abstract
A new polymeric metal organosulfide [CuI3(pymt)3]n (pymt = pyrimidine-2-thiolate) with strong red photoluminescence was synthesized through solvothermal redox reaction, and crystallographically characterized to be a one-dimensional chiral structure containing metal–metal interactions.