Issue 20, 2004
From the journal:

Chemical Communications

Carbon dioxide-expanded liquid substrate phase: an effective medium for selective hydrogenation of cinnamaldehyde to cinnamyl alcohol

Fengyu Zhao,ab   Shin-ichio Fujita,a   Jianmin Sun,a   Yutaka Ikushimabc  and  Masahiko Arai*ab  

* Corresponding authors

a Division of Materials Science and Engineering, Graduate School of Engineering, Hokkaido University, Sapporo, Japan
E-mail: marai@eng.hokudai.ac.jp
Fax: +81-11-7066594
Tel: +81-11-7066594

b CREST, Japan Science and Technology Agency (JST), Saitama, Japan

c Supercritical Fluid Research Center, National Institute of Advanced Industrial Science and Technology, Sendai, Japan

Abstract

It has been shown that CO2-expanded cinnamaldehyde liquid phase is a unique and effective medium for cinnamaldehyde hydrogenation to cinnamyl alcohol, due to interactions between the C[double bond, length as m-dash]O group of the substrate and CO2 molecules and increased solubility of H2.

Graphical abstract: Carbon dioxide-expanded liquid substrate phase: an effective medium for selective hydrogenation of cinnamaldehyde to cinnamyl alcohol

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Article information

DOI
https://doi.org/10.1039/B408434A
Article type
Communication
Submitted
04 Jun 2004
Accepted
29 Jul 2004
First published
07 Sep 2004

Chem. Commun., 2004, 2326-2327

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Carbon dioxide-expanded liquid substrate phase: an effective medium for selective hydrogenation of cinnamaldehyde to cinnamyl alcohol

F. Zhao, S. Fujita, J. Sun, Y. Ikushima and M. Arai, Chem. Commun., 2004, 2326 DOI: 10.1039/B408434A

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