Octahedral metal clusters as building units in a neutral layered honeycomb network, [Zn(en)]2[Nb6Cl12(CN)6]†
Abstract
A polymeric hybrid cluster-based compound with a double-layered honeycomb framework built of octahedral niobium cyanochloride clusters and {Zn(en)}2+ metal complexes was designed and synthesized at room temperature, and structurally characterized by