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Issue 10, 2004
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Well-defined indium(iii) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

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Abstract

Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

Graphical abstract: Well-defined indium(iii) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

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Article information


Submitted
19 Mar 2004
Accepted
08 Apr 2004
First published
16 Apr 2004

Dalton Trans., 2004, 1519-1520
Article type
Communication

Well-defined indium(III) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalyst

J. H. Cotgreave, D. Colclough, G. Kociok-Köhn, G. Ruggiero, C. G. Frost and A. S. Weller, Dalton Trans., 2004, 1519
DOI: 10.1039/B404179H

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