Issue 10, 2004

The thermal and light induced spin transition in [FeL2](BF4)2 (L = 2,6-dipyrazol-1-yl-4-hydroxymethylpyridine)

Abstract

This communication presents the crystal structures of the high spin state at 300 K, the low spin state at 30 K and the metastable high spin state after irradiation at 30 K and an estimate of the critical LIESST temperature of [FeL2](BF4)2 which is shown to undergo a spin transition at 271 K.

Graphical abstract: The thermal and light induced spin transition in [FeL2](BF4)2 (L = 2,6-dipyrazol-1-yl-4-hydroxymethylpyridine)

Supplementary files

Article information

Article type
Communication
Submitted
26 Jan 2004
Accepted
16 Apr 2004
First published
22 Apr 2004

Dalton Trans., 2004, 1516-1518

The thermal and light induced spin transition in [FeL2](BF4)2 (L = 2,6-dipyrazol-1-yl-4-hydroxymethylpyridine)

V. A. Money, J. Elhaïk, M. A. Halcrow and J. A. K. Howard, Dalton Trans., 2004, 1516 DOI: 10.1039/B401155D

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