Issue 19, 2004
From the journal:

Chemical Communications

The surprisingly beneficial effect of soft donors on the performance of early transition metal olefin polymerisation catalysts†

Daniel C. H. Oakes,a   Brian S. Kimberley,a   Vernon C. Gibson,*a   David J. Jones,a   Andrew J. P. Whitea  and  David J. Williamsa  

* Corresponding authors

a Department of Chemistry, Imperial College London, Exhibition Road, London, UK
E-mail: v.gibson@imperial.ac.uk
Fax: +44 (0)20 7594 5810
Tel: +44 (0)20 7594 5830

Abstract

Group 4 metal complexes containing phenoxy-amide ligands bearing soft pendant donors are shown to give more highly active ethylene polymerisation catalysts than counterparts containing hard donors or systems without a pendant donor.

Graphical abstract: The surprisingly beneficial effect of soft donors on the performance of early transition metal olefin polymerisation catalysts

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Article information

DOI
https://doi.org/10.1039/B409870F
Article type
Communication
Submitted
29 Jun 2004
Accepted
13 Jul 2004
First published
23 Aug 2004

Chem. Commun., 2004, 2174-2175

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The surprisingly beneficial effect of soft donors on the performance of early transition metal olefin polymerisation catalysts

D. C. H. Oakes, B. S. Kimberley, V. C. Gibson, D. J. Jones, A. J. P. White and D. J. Williams, Chem. Commun., 2004, 2174 DOI: 10.1039/B409870F

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