Issue 19, 2004

Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes

Abstract

Bis(diethylamino)carbene is kinetically stable to dimerization in THF at ambient temperature; dimer formed during carbene generation arises from reaction of the carbene with the precursor formamidinium ion; this is probably the commonest route to tetraaminoethene dimers, and in a related case the intermediate protonated tetraaminoethene can be observed by NMR.

Graphical abstract: Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes

Article information

Article type
Communication
Submitted
17 Jun 2004
Accepted
29 Jul 2004
First published
20 Aug 2004

Chem. Commun., 2004, 2172-2173

Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes

R. W. Alder, L. Chaker and F. P. V. Paolini, Chem. Commun., 2004, 2172 DOI: 10.1039/B409112D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements