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Issue 20, 2004
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Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

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Abstract

The reaction of various iodophenols with MeMgCl in presence of LiCl followed by the addition of i-PrMgCl provides the corresponding magnesiated magnesium phenolates as THF soluble reagents; this approach can be extended to heterocyclic compounds bearing a hydroxy group like pyridines and quinolines.

Graphical abstract: Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

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Article information


Submitted
25 Jun 2004
Accepted
26 Jul 2004
First published
26 Aug 2004

Chem. Commun., 2004, 2288-2289
Article type
Communication

Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxy group in presence of LiCl

F. Kopp, A. Krasovskiy and P. Knochel, Chem. Commun., 2004, 2288
DOI: 10.1039/B409664A

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