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Issue 12, 2004
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Potassium hexacyanoferrate(ii)—a new cyanating agent for the palladium-catalyzed cyanation of aryl halides

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Abstract

A new advantageous cyanating agent, potassium hexacyanoferrate(II), is described for the palladium-catalyzed cyanation of aryl halides. All cyanide ions on the iron(II) center can be transferred to the aryl halide using palladium(II) acetate and dppf as the catalyst. Under optimized reaction conditions good yields of benzonitriles and unprecedented catalyst productivities are observed.

Graphical abstract: Potassium hexacyanoferrate(ii)—a new cyanating agent for the palladium-catalyzed cyanation of aryl halides

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Article information


Submitted
14 Jan 2004
Accepted
02 Apr 2004
First published
12 May 2004

Chem. Commun., 2004, 1388-1389
Article type
Communication

Potassium hexacyanoferrate(II)—a new cyanating agent for the palladium-catalyzed cyanation of aryl halides

T. Schareina, A. Zapf and M. Beller, Chem. Commun., 2004, 1388 DOI: 10.1039/B400562G

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