Issue 12, 2004
From the journal:

Chemical Communications

Thermal and light induced polymorphism in iron(ii) spin crossover compounds†

Amber L. Thompson,a   Andrés E. Goeta,*a   José A. Real,*b   Ana Galetc  and  M. Carmen Muñozc  

* Corresponding authors

a Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: A.E.Goeta@durham.ac.uk
Fax: +44 191 384 4737
Tel: +44 191 334 2102

b Institut de Ciencia Molecular/Departament de Química Inorgánica, Universitat de València, Doctor Moliner 50, Burjassot, Spain
E-mail: jose.a.real@uv.es

c Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46071, Valencia, Spain

Abstract

The spin crossover complexes {Fe[H2B(pz)2]2L} ([H2B(pz)2]− = dihydrobis(pyrazolyl)borate, L = 2,2′-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for 2 are different from that of the thermally induced high spin state and from those of 1.

Graphical abstract: Thermal and light induced polymorphism in iron(ii) spin crossover compounds

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Article information

DOI
https://doi.org/10.1039/B403179B
Article type
Communication
Submitted
03 Mar 2004
Accepted
14 Apr 2004
First published
14 May 2004

Chem. Commun., 2004, 1390-1391

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Thermal and light induced polymorphism in iron(II) spin crossover compounds

A. L. Thompson, A. E. Goeta, J. A. Real, A. Galet and M. Carmen Muñoz, Chem. Commun., 2004, 1390 DOI: 10.1039/B403179B

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