Issue 3, 2003
From the journal:

New Journal of Chemistry

Vanadium phosphorus oxide as an efficient catalyst for hydrocarbon oxidations using hydrogen peroxide

Unnikrishnan R. Pillaia  and  Endalkachew Sahle-Demessie*a  

* Corresponding authors

a National Risk Management Research Laboratory, Sustainable Technology Division, MS 443, United States Environmental Protection Agency, Cincinnati, Ohio, USA
E-mail: Sahle-Demessie.Endalkachew@epa.gov
Fax: +1 513 569 7677

Abstract

Calcined vanadium phosphorus oxide (VPO) prepared by an organic route is found to be an active and effective catalyst for the oxidation of various alkanes such as cyclopentane, cyclohexane, n-hexane, cycloheptane, cyclooctane, cyclodecane and adamantane in acetonitrile solvent using the environmentally benign oxidant, hydrogen peroxide, where the oxidation mechanism is believed to involve a reversible V4+/V5+ redox cycle.

Graphical abstract: Vanadium phosphorus oxide as an efficient catalyst for hydrocarbon oxidations using hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/B209268A
Article type
Paper
Submitted
20 Sep 2002
Accepted
27 Nov 2002
First published
04 Feb 2003

New J. Chem., 2003,27, 525-528

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Vanadium phosphorus oxide as an efficient catalyst for hydrocarbon oxidations using hydrogen peroxide

U. R. Pillai and E. Sahle-Demessie, New J. Chem., 2003, 27, 525 DOI: 10.1039/B209268A

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