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Issue 2, 2003
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Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2

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Abstract

Four chiral perfluoroalkylated monodentate phosphorus(III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO2) and compared with the parent, non-perfluoroalkylated, catalyst systems.

Graphical abstract: Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2

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Article information


Submitted
11 Dec 2002
First published
27 Mar 2003

Green Chem., 2003,5, 118-122
Article type
Paper

Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(III) ligands in supercritical CO2 and CH2Cl2

D. J. Adams, W. Chen, E. G. Hope, S. Lange, A. M. Stuart, A. West and J. Xiao, Green Chem., 2003, 5, 118
DOI: 10.1039/B212313B

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