Issue 24, 2003

Synthesis and structure of a new aluminium citrate trimer from aqueous solution at very low pH

Abstract

A novel trinuclear Al(III) citrate complex, [Al(H2O)6][(Al3(C6H4O7)2(OH)2(H2O)4]2(NO3)·6H2O, can be synthesised from solutions containing 1 ∶ 1 and 10 ∶ 1 aluminium to citrate ratios providing the pH is within the range 1.2–3.0.

Graphical abstract: Synthesis and structure of a new aluminium citrate trimer from aqueous solution at very low pH

Supplementary files

Article information

Article type
Communication
Submitted
01 Oct 2003
Accepted
27 Oct 2003
First published
03 Nov 2003

Dalton Trans., 2003, 4572-4573

Synthesis and structure of a new aluminium citrate trimer from aqueous solution at very low pH

S. A. Malone, P. Cooper and S. L. Heath, Dalton Trans., 2003, 4572 DOI: 10.1039/B312176C

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