Issue 24, 2003
From the journal:

Dalton Transactions

Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide

Michael S. Hill*a  and  Peter B. Hitchcockb  

* Corresponding authors

a Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London, UK
E-mail: mike.hill@imperial.ac.uk
Fax: +44 (0)20 7594 5804
Tel: +44 (0)207 594 5709

b The Chemistry Laboratory, University of Sussex, Falmer, East Sussex, UK

Abstract

Reaction of two molar equivalents of [KN(SiMe3)2] and a mixture of [CH2(Ph2P[double bond, length as m-dash]NC6H2-Me3-2,4,6)2] and SmI2 in THF resulted in the formation of a stable homoleptic samarium dialkyl without additional solvent coordination.

Graphical abstract: Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide

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Article information

DOI
https://doi.org/10.1039/B313034G
Article type
Communication
Submitted
16 Oct 2003
Accepted
30 Oct 2003
First published
31 Oct 2003

Dalton Trans., 2003, 4570-4571

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Synthesis of a homoleptic Sm(II) bis(phosphinimino)methanide

M. S. Hill and P. B. Hitchcock, Dalton Trans., 2003, 4570 DOI: 10.1039/B313034G

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