Silver(i) complex of a new imino-N-heterocyclic carbene and ligand transfer to palladium(ii) and rhodium(i)†
Abstract
A new imino-N-heterocyclic N(i-Pr)}] bromide has been synthesised and structurally characterised. The silver(I) complex [Ag(C⁁imine)2]AgBr2, where (C⁁imine)
= 1-(2,4,6-Me3C6H2)imidazol-2-ylidene-3-{CH2C(t-Bu)
N(i-Pr)}, was readily prepared by reaction with Ag2O. Transfer of the
C(t-Bu)NH(i-Pr)}.