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Issue 19, 2003
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Sulfoxide-directed thermal intramolecular [4 + 2] cycloadditions between 2-sulfinyl butadienes and unactivated alkynes

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Abstract

2-Sulfinyl butadienes tethered to unactivated alkynes undergo a facile thermal intramolecular Diels–Alder cycloaddition, often at room temperature, to produce cyclohexa-1,4-dienes with good selectivities, in high yields, and preserving the valuable vinyl sulfoxide functionality.

Graphical abstract: Sulfoxide-directed thermal intramolecular [4 + 2] cycloadditions between 2-sulfinyl butadienes and unactivated alkynes

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Publication details

The article was received on 01 Jul 2003, accepted on 05 Aug 2003 and first published on 28 Aug 2003


Article type: Communication
DOI: 10.1039/B307485D
Citation: Chem. Commun., 2003,0, 2476-2477

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    Sulfoxide-directed thermal intramolecular [4 + 2] cycloadditions between 2-sulfinyl butadienes and unactivated alkynes

    R. Fernández de la Pradilla, R. Baile and M. Tortosa, Chem. Commun., 2003, 0, 2476
    DOI: 10.1039/B307485D

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