Issue 19, 2003
From the journal:

Chemical Communications

Bidentate ligands formed by self-assembly†

Vincent F. Slagt,a   Piet W. N. M. van Leeuwena  and  Joost N. H. Reek*a  

* Corresponding authors

a Institute of molecular chemistry, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam, The Netherlands
E-mail: reek@science.uva.nl
Fax: (+31) 20-5256422
Tel: (+31) 20-5256960

Abstract

A novel supramolecular strategy to prepare bidentate ligands via the assembly of functionalised monomeric ligands on a dimeric zinc(II) porphyrin template is presented; the assembled bidentate ligands show chelating behaviour and their rhodium complexes display enhanced selectivity in the hydroformylation compared to the non-template analogue.

Graphical abstract: Bidentate ligands formed by self-assembly

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Article information

DOI
https://doi.org/10.1039/B306683E
Article type
Communication
Submitted
12 Jun 2003
Accepted
05 Aug 2003
First published
02 Sep 2003

Chem. Commun., 2003, 2474-2475

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Bidentate ligands formed by self-assembly

V. F. Slagt, P. W. N. M. van Leeuwen and J. N. H. Reek, Chem. Commun., 2003, 2474 DOI: 10.1039/B306683E

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