Mono(sulfido)-bridged mixed-valence nitrosyl complex: protonation and oxidative addition of iodine across the Ir(ii)–Ir(0) bond†
Abstract
Treatment of [Cp*IrH(SH)(PMe3)] (Cp* = η5-C5Me5) with [IrCl2(NO)(PPh3)2] in the presence of
* Corresponding authors
a Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan
b
Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, Japan
E-mail:
skuwata@o.cc.titech.ac.jp
c
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, Kasuga, Bunkyo-ku, Tokyo, Japan
E-mail:
ishii@chem.chuo-u.ac.jp
d
Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Tokyo University of Science, Noda, Chiba, Japan
E-mail:
hidai@rs.noda.tus.ac.jp
Treatment of [Cp*IrH(SH)(PMe3)] (Cp* = η5-C5Me5) with [IrCl2(NO)(PPh3)2] in the presence of
T. Hattori, S. Matsukawa, S. Kuwata, Y. Ishii and M. Hidai, Chem. Commun., 2003, 510 DOI: 10.1039/B211021K
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