Issue 4, 2003
From the journal:

Chemical Communications

First example of a tetra-carboxylate bridged dimanganese species†

Abdessamad Grirrane,a   Antonio Pastor,a   Agustín Galindo,*a   Andrea Ienco,b   Carlo Mealli*b  and  Patrick Rosac  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 553, Sevilla, Spain

b ICCOM, CNR, Via Nardi 39, Firenze, Italy

c Dipartimento di Chimica, Via della Lastruccia 3, Sesto Fiorentino, Firenze, Italy

Abstract

The compound [Mn(tda)(bipy)] (tda = S(CH2COO)22−) features the first structurally characterized tetra-carboxylate dimanganese antiferromagnetic system with ‘copper acetate’ core; the binuclear units, completed by bipyridine chelates, are doubly chained by the tda anions that adopt an unprecedented μ,μ′-η1,η1,η1,η1 coordination mode.

Graphical abstract: First example of a tetra-carboxylate bridged dimanganese species

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Article information

DOI
https://doi.org/10.1039/B211886F
Article type
Communication
Submitted
29 Nov 2002
Accepted
13 Jan 2003
First published
23 Jan 2003

Chem. Commun., 2003, 512-513

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First example of a tetra-carboxylate bridged dimanganese species

A. Grirrane, A. Pastor, A. Galindo, A. Ienco, C. Mealli and P. Rosa, Chem. Commun., 2003, 512 DOI: 10.1039/B211886F

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