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Issue 18, 2003
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Heterobimetallic lithium alkyltriimido aluminate cages containing the [R′Al(NR)3]4− tetraanion (R′ = Bun, Et; R = 2-OMeC6H4)

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Abstract

Attempted metallation of a triamidoaluminane gives a complex containing the [R′Al(NR) 3 ] 4− anion whose formal tetranegative charge is the highest charge observed crystallographically for a simple mononuclear imido main group anion system.
Graphical abstract: Heterobimetallic lithium alkyltriimido aluminate cages containing the [R′Al(NR)3]4− tetraanion (R′ = Bun, Et; R = 2-OMeC6H4)

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Article information


Submitted
03 Jul 2003
Accepted
01 Aug 2003
First published
12 Aug 2003

Chem. Commun., 2003, 2356-2357
Article type
Communication

Heterobimetallic lithium alkyltriimido aluminate cages containing the [R′Al(NR)3]4− tetraanion (R′ = Bun, Et; R = 2-OMeC6H4)

M. C. Copsey, J. C. Jeffery, C. A. Russell, J. M. Slattery and J. A. Straughan, Chem. Commun., 2003, 2356
DOI: 10.1039/B307589C

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