Issue 18, 2003

Solid-supported stereospecific living Ziegler–Natta polymerization of α-olefins

Abstract

A successful strategy has been developed for the synthesis of a cationic pentamethylcyclopentadienyl zirconium amidinate initiator on a lightly crosslinked polystyrene-divinylbenzene support that can be used to polymerize α-olefins in a living and stereospecific fashion.

Graphical abstract: Solid-supported stereospecific living Ziegler–Natta polymerization of α-olefins

Article information

Article type
Communication
Submitted
02 Jul 2003
Accepted
24 Jul 2003
First published
12 Aug 2003

Chem. Commun., 2003, 2358-2359

Solid-supported stereospecific living Ziegler–Natta polymerization of α-olefins

Y. Zhang and L. R. Sita, Chem. Commun., 2003, 2358 DOI: 10.1039/B307555A

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