Acylated oxazolidinones and bornane sultams can be cleaved to divinyl- and diallylcarbinols by treatment with vinyl- or allylmetal compounds. For the preparation of divinylcarbinols, acylated bornane sultams are the starting materials of choice, while for the preparation of diallylcarbinols acylated oxazolidinones and bornane sultams work equally well.
B. Schmidt and H. Wildemann, J. Chem. Soc., Perkin Trans. 1, 2002, 1050 DOI: 10.1039/B200976E
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