A rare ether-bridged cobalt complex which gives rise to an unusual ‘serpentine’ metal–ligand binding motif

Garry Mund; Andrea J. Gabert; Raymond J. Batchelor; James F. Britten; Daniel B. Leznoff

doi:10.1039/B208221G

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A rare ether-bridged cobalt complex which gives rise to an unusual ‘serpentine’ metal–ligand binding motif

Garry Mund,^a Andrea J. Gabert,^a Raymond J. Batchelor,^a James F. Britten^a and Daniel B. Leznoff*^a

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* Corresponding authors

^a Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, B.C, Canada
E-mail: dleznoff@sfu.ca
Fax: 1-604-291-3765
Tel: 1-604-291-4887

Abstract

An unusual metal–ligand binding motif is found in dimeric cobalt(II) complexes coordinated by diamidoether ligands that bridge the metals in a ‘serpentine’ fashion through the ether donors of the ligand backbone rather than the amido groups.

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Supplementary files

Crystal structure data TXT (46K)

Article information

DOI: https://doi.org/10.1039/B208221G
Article type: Communication
Submitted: 22 Aug 2002
Accepted: 25 Oct 2002
First published: 12 Nov 2002

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Chem. Commun., 2002, 2990-2991

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A rare ether-bridged cobalt complex which gives rise to an unusual ‘serpentine’ metal–ligand binding motif

G. Mund, A. J. Gabert, R. J. Batchelor, J. F. Britten and D. B. Leznoff, Chem. Commun., 2002, 2990 DOI: 10.1039/B208221G

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Chemical Communications

A rare ether-bridged cobalt complex which gives rise to an unusual ‘serpentine’ metal–ligand binding motif

Abstract

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A rare ether-bridged cobalt complex which gives rise to an unusual ‘serpentine’ metal–ligand binding motif

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