Issue 24, 2002
From the journal:

Chemical Communications

Charge-transfer band shifts in iron(iii) hexacyanoferrate(ii) by electro-intercalated cationsvia ground state-energy/lattice-energy link

David R. Rosseinsky,†*a   Hanyong Lim,ab   Xiao Zhang,a   Hongjin Jiangc  and  Jian Wei Chaia  

* Corresponding authors

a Singapore Institute of Mfg. Technology, 71 Nanyang Drive, Singapore

b Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213-3890, USA

c Finisar Singapore Pte Ltd, Unit 2-30 The Alpha, 10 Science Park Rd II, Science Park ii, Singapore, 117684

d Institute of Materials Research & Engineering, 3 Research Link, Singapore

Abstract

It is currently important to achieve and understand adjustments of optical properties: “guest cation” induced CT spectral shifts in Prussian Blue are shown to be driven (via its specific effect on the Fe(CN)6 CT-donor entity) by the cation lattice-energy interaction, as inferred from microgravimetry of introduced alkali-metal ions, and from independent solubility correlations for other intercalated cations.

Graphical abstract: Charge-transfer band shifts in iron(iii) hexacyanoferrate(ii) by electro-intercalated cations via ground state-energy/lattice-energy link

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B209708G
Article type
Communication
Submitted
07 Oct 2002
Accepted
24 Oct 2002
First published
08 Nov 2002

Chem. Commun., 2002, 2988-2989

Permissions

Request permissions

Charge-transfer band shifts in iron(III) hexacyanoferrate(II) by electro-intercalated cations via ground state-energy/lattice-energy link

D. R. Rosseinsky, H. Lim, X. Zhang, H. Jiang and J. Wei Chai, Chem. Commun., 2002, 2988 DOI: 10.1039/B209708G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements