Issue 24, 2002
From the journal:

Chemical Communications

Catalytic insertion of diazo compounds into N–H bonds: the copper alternative

M. Esther Morilla,a   M. Mar Díaz-Requejo,a   Tomás R. Belderrain,a   M. Carmen Nicasio,a   Swiatoslaw Trofimenkob  and  Pedro J. Pérez*a  

* Corresponding authors

a Departamento de Química y Ciencia de los Materiales, Universidad de Huelva, Carretera de Palos de la Ffrontera s/n, Huelva, Spain
E-mail: perez@dqcm.uhu.es
Fax: +34 959 017414
Tel: +34 959 0174112

b Department of Chemistry and Biochemistry, University of Delaware, Newark, DE, USA

Abstract

The complexes TpXCu (TpX = homoscorpionate) catalyse the insertion of diazo compounds into nitrogen–hydrogen bonds of amines and amides, under very mild conditions, with quantitative yields being obtained with equimolar ratios of reactants.

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Article information

DOI
https://doi.org/10.1039/B207389G
Article type
Communication
Submitted
26 Jul 2002
Accepted
21 Oct 2002
First published
11 Nov 2002

Chem. Commun., 2002, 2998-2999

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Catalytic insertion of diazo compounds into N–H bonds: the copper alternative

M. E. Morilla, M. M. Díaz-Requejo, T. R. Belderrain, M. C. Nicasio, S. Trofimenko and P. J. Pérez, Chem. Commun., 2002, 2998 DOI: 10.1039/B207389G

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