Issue 24, 2002
From the journal:

Chemical Communications

The first structural characterization and determination of the isomerization activation parameters of a chiral phosphatitanocene†

T. Keith Hollis,*a   Yi Joon Ahna  and  Fook S. Thama  

* Corresponding authors

a Department of Chemistry, University of California, Riverside, CA, USA
E-mail: keith.hollis@ucr.edu
Fax: +909-787-4713
Tel: +909-787-3024

Abstract

The activation parameters (ΔG‡298 = 11.5 (±1.0) kcal mol−1, ΔH‡ = 16.3 (±3.0) kcal mol−1, ΔS‡ = 16 (±11) cal mol−1 K−1) have been determined for the rac to meso isomerization of a phosphametallocene, bis(3,4-dimethyl-2-phenylphospholyl)titanium dichloride, 2, which has been structurally characterized.

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Article information

DOI
https://doi.org/10.1039/B208945A
Article type
Communication
Submitted
13 Sep 2002
Accepted
24 Oct 2002
First published
11 Nov 2002

Chem. Commun., 2002, 2996-2997

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The first structural characterization and determination of the isomerization activation parameters of a chiral phosphatitanocene

T. K. Hollis, Y. J. Ahn and F. S. Tham, Chem. Commun., 2002, 2996 DOI: 10.1039/B208945A

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