Issue 17, 2002
From the journal:

Chemical Communications

Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

Vernon C. Gibson,*a   Rachel K. O’Reilly,a   Warren Reed,b   Duncan F. Wass,b   Andrew J. P. Whitea  and  David J. Williamsa  

* Corresponding authors

a Department of Chemistry, Imperial College, Exhibition Road, South Kensington, London, UK
E-mail: v.gibson@ic.ac.uk
Fax: 020 7594 5810
Tel: 020 7594 5830

b BP Chemicals, Sunbury Research Centre, Chertsey Road, Middlesex, Sunbury on Thames, UK
E-mail: WassDF@bp.com
Fax: 01932 775467
Tel: 01932 775247

Abstract

Four-coordinate iron(II) complexes bearing α-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive β-hydrogen chain transfer processes.

Graphical abstract: Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

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Article information

DOI
https://doi.org/10.1039/B204510A
Article type
Communication
Submitted
10 May 2002
Accepted
12 Jul 2002
First published
24 Jul 2002

Chem. Commun., 2002, 1850-1851

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Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

V. C. Gibson, R. K. O’Reilly, W. Reed, D. F. Wass, A. J. P. White and D. J. Williams, Chem. Commun., 2002, 1850 DOI: 10.1039/B204510A

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