Issue 17, 2002
From the journal:

Chemical Communications

Intramolecular dealkylation of chelating diamines with Ru(ii) complexes

M. Esther Morilla,a   Galanda Morfes,b   M. Carmen Nicasio,a   Tomás R. Belderrain,a   M. Mar Díaz-Requejo,a   Claudia Graiff,c   Antonio Tiripicchio,c   Roberto Sánchez-Delgado*b  and  Pedro J. Pérez*a  

* Corresponding authors

a Departamento de Química y Ciencia de los Materiales, Universidad de Huelva, Carretera de Palos de la Frontera s/n, Huelva, Spain
E-mail: perez@dqcm.uhu.es
Fax: +34 959 017414
Tel: +34 959 017411

b Instituto Venezolano de Investigaciones Científicas, Apartado 21827, Caracas 1020-A, Venezuela

c Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma, Parco Area delle Scienze 17A, Parma, Italy

Abstract

N,N, N′,N′-Tetraethylethylenediamine undergoes simple or double intramolecular dealkylation reactions in the presence of the complexes [RuCl2(diene)]n (diene = cod, nbd) or trans-[RuCl2(diene)(morfoline)2 at 80 °C to afford chelating amine ligands which contains one or two N–H functionalities.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B205078A
Article type
Communication
Submitted
27 May 2002
Accepted
08 Jul 2002
First published
24 Jul 2002

Chem. Commun., 2002, 1848-1849

Permissions

Request permissions

Intramolecular dealkylation of chelating diamines with Ru(II) complexes

M. E. Morilla, G. Morfes, M. C. Nicasio, T. R. Belderrain, M. M. Díaz-Requejo, C. Graiff, A. Tiripicchio, R. Sánchez-Delgado and P. J. Pérez, Chem. Commun., 2002, 1848 DOI: 10.1039/B205078A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements