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Issue 17, 2002
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Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

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Abstract

Four-coordinate iron(II) complexes bearing α-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive β-hydrogen chain transfer processes.

Graphical abstract: Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

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Article information


Submitted
10 May 2002
Accepted
12 Jul 2002
First published
24 Jul 2002

Chem. Commun., 2002, 1850-1851
Article type
Communication

Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

V. C. Gibson, R. K. O’Reilly, W. Reed, D. F. Wass, A. J. P. White and D. J. Williams, Chem. Commun., 2002, 1850
DOI: 10.1039/B204510A

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