Issue 14, 2001
From the journal:

Chemical Communications

Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation–recombination of the Si–Cl bond

Vijeyakumar Kingston,a   Boris Gostevskii,a   Inna Kalikhman*a  and  Daniel Kost*a  

* Corresponding authors

a Department of Chemistry, Ben-Gurion University, Beer-Sheva, Israel.
E-mail: kostd@bgumail.bgu.ac.il

Abstract

Equilibrium between neutral hexacoordinate silicon complexes and ionic siliconium chlorides, which is highly temperature, solvent, counterion, ligand and substituent dependent, was observed by low temperature 29Si NMR and confirmed by crystal analysis.

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Article information

DOI
https://doi.org/10.1039/B102427M
Article type
Communication
Submitted
14 Mar 2001
Accepted
25 May 2001
First published
21 Jun 2001

Chem. Commun., 2001, 1272-1273

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Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation–recombination of the Si–Cl bond

V. Kingston, B. Gostevskii, I. Kalikhman and D. Kost, Chem. Commun., 2001, 1272 DOI: 10.1039/B102427M

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