Issue 13, 2001
From the journal:

Chemical Communications

A self-assembled novel octanuclear Cu(II) ‘pin-wheel’ cluster exhibiting ferromagnetic coupling

Zhiqiang Xu,a   Laurence K. Thompson*a  and  David O. Millera  

* Corresponding authors

a Department of Chemistry, Memorial University of Newfoundland, St. John’s, NFLD, Canada
E-mail: lthomp@morgan.ucs.mun.ca

Abstract

The heptadentate, ‘tritopic’ ligand 2poapH2 reacts with Cu(NO3)2 in the presence of Gd(NO3)3 to give a novel, self-assembled, ferromagnetically coupled, alkoxide bridged octanuclear Cu(II) cluster in the shape of a pin-wheel, with a central Cu4[μ-O4] core, and isolated Curie-like [Gd(NO3)4(H2O)2]− anions.

Graphical abstract: A self-assembled novel octanuclear Cu() ‘pin-wheel’ cluster exhibiting ferromagnetic coupling

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Article information

DOI
https://doi.org/10.1039/B101966J
Article type
Communication
Submitted
01 Mar 2001
Accepted
14 May 2001
First published
05 Jun 2001

Chem. Commun., 2001, 1170-1171

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A self-assembled novel octanuclear Cu(II) ‘pin-wheel’ cluster exhibiting ferromagnetic coupling

Z. Xu, L. K. Thompson and D. O. Miller, Chem. Commun., 2001, 1170 DOI: 10.1039/B101966J

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