The tris(dimethylphosphinomethyl)-substituted lithium alkoxide [LiOC(CH2PMe2)3] acts as a building block in mixed polylithium aggregates, effectively capping triangular Li3 polyhedral faces; it further reacts with lithium organyls to yield the Y-conjugated, symmetrically tris(dimethylphosphino)-substituted trimethylenemethane dianion.
A multidentate phosphinoalkoxide ligand as a building block in mixed polylithium aggregates
A. Feustel and G. Müller, Chem. Commun., 2001, 1024 DOI: 10.1039/B010115J
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