Issue 11, 2001
From the journal:

Chemical Communications

The best structural model of ADH so far: a pyrazolylbis(thioimidazolyl)borate zinc ethanol complex

Jan Seebacher,a   Mouhai Shua  and  Heinrich Vahrenkamp*a  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie der Universität Freiburg, Albertstr. 21, Freiburg, Germany.

Abstract

The new N,S,S ligand [HB(timo-An)2(pzPh,Me)] − (L1) was combined with zinc perchlorate and ethanol to form the complex [L1·Zn(ethanol)]ClO4 which is the first zinc complex in which the N,S,S ligation of zinc and the attachment of ethanol occurring in the active center of horse liver alcoholdehydrogenase (ADH) have been reproduced; the structural details of the ZnNS2O coordination in the complex and in DMSO-inhibited ADH are in reasonably good agreement.

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Article information

DOI
https://doi.org/10.1039/B100281N
Article type
Communication
Submitted
08 Jan 2001
Accepted
17 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1026-1027

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The best structural model of ADH so far: a pyrazolylbis(thioimidazolyl)borate zinc ethanol complex

J. Seebacher, M. Shu and H. Vahrenkamp, Chem. Commun., 2001, 1026 DOI: 10.1039/B100281N

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