Issue 4, 2001
From the journal:

Chemical Communications

1,1′-Bis(trimethylsilylseleno)ferrocene in cluster synthesis: a redox active surface on a copper–selenide coreElectronic supplementary information (ESI) available: cyclic voltammograms for 1 and 2, 1H NMR spectrum for 1. See http://www.rsc.org/suppdata/cc/b0/b010023o/Dedicated to Dr Arthur J. Carty on the occasion of his 60th birthday.

Andrew I. Wallbanka  and  John F. Corrigan*a  

* Corresponding authors

a Department of Chemistry, The University of Western Ontario, Ontario, London, Canada.
E-mail: jfcorrig@julian.uwo.ca

Abstract

1,1′-Bis(trimethylsilylseleno)ferrocene 1 has been prepared from the reaction of [1,1′-Fe(η5-C5H4SeLi)2 (TMEDA)] and ClSiMe3 in good yield. The reactive silyl groups on 1 are used as a driving force for the synthesis of [Cu8{Fe(η5-C5H4Se) 2}4(PPh2Et)4] 2, a cluster possessing four peripheral ferrocenyl moieties.

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Article information

DOI
https://doi.org/10.1039/B010023O
Article type
Communication
Submitted
15 Dec 2000
Accepted
17 Jan 2001
First published
08 Feb 2001

Chem. Commun., 2001, 377-378

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1,1′-Bis(trimethylsilylseleno)ferrocene in cluster synthesis: a redox active surface on a copper–selenide core

A. I. Wallbank and J. F. Corrigan, Chem. Commun., 2001, 377 DOI: 10.1039/B010023O

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