[ButNHP(μ-NBut)2PNH2], a novel building block for neutral and anionic polycyclic main group arrangements

Michael A. Beswick; Benjamin R. Elvidge; Neil Feeder; Sara J. Kidd; Dominic S. Wright

doi:10.1039/B009000J

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[Bu^tNHP(μ-NBu^t)₂PN H₂], a novel building block for neutral and anionic polycyclic main group arrangementsElectronic supplementary information (ESI) available: synthetic and crystallographic details for 1–3, See http://www.rsc.org/suppdata/cc/b0/b009000j/

Michael A. Beswick,*^a Benjamin R. Elvidge,^a Neil Feeder,^a Sara J. Kidd^a and Dominic S. Wright*^a

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* Corresponding authors

^a University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

Abstract

The novel precursor [Bu^tNHP(μ-NBu^t)₂PNH₂] (1) provides easy access to polycyclic main group systems; reaction with Sb(NMe₂)₃ gives the tricyclic species {[Bu^tNHP(μ-NBu^t)₂- P}₂{Me₂NSb(μ-N)}₂] (2), whereas reaction with an excess of BuⁿLi results in elimination of LiNH₂ and the formation of the co-complex [{Bu^tNP(μ-NBu^t)₂P}₂N]Li₃ (BuⁿLi)₂, (3), containing the unprecedented [{Bu^tNP(μ-NBu^t)₂P}₂N]³⁻ trianion.

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Article information

DOI: https://doi.org/10.1039/B009000J
Article type: Communication
Submitted: 08 Nov 2000
Accepted: 17 Jan 2001
First published: 08 Feb 2001

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Chem. Commun., 2001, 379-380

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[Bu^tNHP(μ-NBu^t)₂PN H₂], a novel building block for neutral and anionic polycyclic main group arrangements

M. A. Beswick, B. R. Elvidge, N. Feeder, S. J. Kidd and D. S. Wright, Chem. Commun., 2001, 379 DOI: 10.1039/B009000J

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