Issue 20, 2001

Alkaneoxidation by a carboxylate-bridged dimanganese(iii) complex

Abstract

A new manganese(III) oxamato dimer possesing an unprecedented Mn2(μ-O2CR)(μ-OH2⋯O2 CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by ButO2H and O2 in CH2Cl2 at rt.

Supplementary files

Article information

Article type
Communication
Submitted
12 Jun 2001
Accepted
06 Sep 2001
First published
01 Oct 2001

Chem. Commun., 2001, 2102-2103

Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

G. Blay, I. Fernández, T. Giménez, J. R. Pedro, R. Ruiz, E. Pardo, F. Lloret and M. C. Muñoz, Chem. Commun., 2001, 2102 DOI: 10.1039/B105132F

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