Issue 20, 2001
From the journal:

Chemical Communications

Triprotic 2,4,6-tris(organoamino)-1,3,5-triazenes as precursors to multi-site triazenate

Frederic Rivalsa  and  Alexander Steiner*a  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: A.Steiner@liv.ac.uk

Abstract

2,4,6-Tris(2-fluoroanilino)-1,3,5-triazene successively undergoes one-, two- and three-fold deprotonation in the presence of BunLi; the dilithiated triazenate exists as the dimeric complex (thf)6Li4[(RN)2(RNH)C3N3 ]2 in the solid state (R = 2-F-C6H4) featuring bidentate Nendo–C–Nexo chelation sites.

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Article information

DOI
https://doi.org/10.1039/B105435J
Article type
Communication
Submitted
20 Jun 2001
Accepted
06 Sep 2001
First published
01 Oct 2001

Chem. Commun., 2001, 2104-2105

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Triprotic 2,4,6-tris(organoamino)-1,3,5-triazenes as precursors to multi-site triazenate ligands

F. Rivals and A. Steiner, Chem. Commun., 2001, 2104 DOI: 10.1039/B105435J

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