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Issue 11, 2001
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Synthesis and structure of [Sn9(Ndmp)7(HNdmp)2O2], containing a bidentate double-cubaneoxo fragment (H2Ndmp= 2-amino- 4,6-dimethoxypyrimidine

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The reaction of Sn(NMe2)2 with H2Ndmp (H2Ndmp = 2-amino-4,6-dimethoxypyrimidine) and H2O (ca. 4∶4∶1 equivalents, respectively) gives the cage complex [Sn9(Ndmp)7(HNdmp)2O2] 1, containing an oxo double-cubane fragment [Sn7(Ndmp)6O2] coordinated to a neutral (HNdmpSn)2(μ-Ndmp) unit; 1 is the largest imido Sn(II) complex so far characterised.

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Article information

07 Feb 2001
19 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1010-1011
Article type

Synthesis and structure of [Sn9(Ndmp)7(HNdmp)2O2], containing a bidentate double-cubane oxo fragment (H2Ndmp= 2-amino- 4,6-dimethoxypyrimidine

N. Feeder, E. A. Harron, M. E. G. Mosquera, A. D. Woods and D. S. Wright, Chem. Commun., 2001, 1010
DOI: 10.1039/B101247I

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