Issue 11, 2001
From the journal:

Chemical Communications

First observation of a ferromagnetic interaction through an end-to-end azido bridging pathway in a 1D copper(ii) system

Tapas Kumar Maji,a   Partha Sarathi Mukherjee,a   Golam Mostafa,b   Talal Mallah,*c   Joan Cano-Boquerac  and  Nirmalendu Ray Chaudhuri*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta–, India.
E-mail: icnrc@mahendra.iacs.res.in

b Department of Physics, Krishnath College, Berhampur–, India

c Laboratoire de Chimie Inorganique, UMR CNRS 8613, Université Paris-Sud, Orsay, France

Abstract

A novel one-dimensional copper(II) compound [Cu(L)(μ1,3-N3)(ClO4)]n [L = tridentate Schiff base, formed by condensation of pyridine-2-aldehyde and 1-(2-aminoethyl)piperidine] has been synthesized and structurally characterized; it exhibits ferromagnetic interaction via end-to-end azido (μ1,3-N3) linkages, as rationalised by DFT calculation.

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Article information

DOI
https://doi.org/10.1039/B100529O
Article type
Communication
Submitted
15 Jan 2001
Accepted
05 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1012-1013

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First observation of a ferromagnetic interaction through an end-to-end azido bridging pathway in a 1D copper(II) system

T. K. Maji, P. S. Mukherjee, G. Mostafa, T. Mallah, J. Cano-Boquera and N. R. Chaudhuri, Chem. Commun., 2001, 1012 DOI: 10.1039/B100529O

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