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Issue 15, 2001
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Unexpected reactivity of two-coordinate palladium–carbene complexes; synthetic and catalytic implicationsElectronic supplementary information (ESI) available: details of experimental procedures and characterisation data for complexes 2–6, ligand substitution reactions and general procedure for coupling reactions. See http://www.rsc.org/suppdata/cc/b1/b104297c/

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Abstract

Ligand exchange reactions reveal unexpected lability of the carbene ligands in two coordinate palladium(0) N-heterocyclic carbene complexes; the latter are found to be very effective catalysts for amination of aryl chlorides.

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Article information


Submitted
16 May 2001
Accepted
21 Jun 2001
First published
11 Jul 2001

Chem. Commun., 2001, 1388-1389
Article type
Communication

Unexpected reactivity of two-coordinate palladium–carbene complexes; synthetic and catalytic implications

L. R. Titcomb, S. Caddick, F. G. N. Cloke, D. J. Wilson and D. McKerrecher, Chem. Commun., 2001, 1388 DOI: 10.1039/B104297C

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