Issue 10, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Nickel catalyzed cascade conversion of propargyl halide and propargyl alcohol into 4,6-dimethyl-5-cyano-2-pyrone in water

Noé Rosas,a   Manuel Salmon,a   Pankaj Sharma,a   Cecilio Alvarez,a   Rodrigo Ramirez,a   José-Luis Garciaa  and  Henri Arzoumanian*b  

* Corresponding authors

a Instituto de Quimica, UNAM, Circuito Exterior C.U. Mexico D.F.

b UMR 6516 du CNRS, ENSSPICAM, Faculté des Sciences St Jérôme, Marseille, France

Abstract

Reaction of propargyl halide or alcohol with CO and KCN in the presence of Ni(CN)2 in a basic aqueous medium affords 4,6-dimethyl-5-cyano-2-pyrone.

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Article information

DOI
https://doi.org/10.1039/B002338H
Article type
Communication
Submitted
24 Mar 2000
Accepted
30 Mar 2000
First published
28 Apr 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 1493-1494

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Nickel catalyzed cascade conversion of propargyl halide and propargyl alcohol into 4,6-dimethyl-5-cyano-2-pyrone in water

N. Rosas, M. Salmon, P. Sharma, C. Alvarez, R. Ramirez, J. Garcia and H. Arzoumanian, J. Chem. Soc., Perkin Trans. 1, 2000, 1493 DOI: 10.1039/B002338H

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