Issue 10, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

A new reaction of arylphospholes: site-selective phosphorylation through reaction with phosphorus tribromide

György Keglevich,*a   Tungalag Chuluunbaatar,a   András Dobób  and  László Tőkec  

* Corresponding authors

a Department of Organic Chemical Technology, Budapest University of Technology and Economics, Budapest, Hungary
E-mail: keglevich@oct.bme.hu

b Hungarian Academy of Sciences, Chemical Research Center, Budapest, Hungary

c Research Group of the Hungarian Academy of Sciences at the Department of Organic Chemical Technology, Budapest University of Technology and Economics, Budapest, Hungary

Abstract

The reaction of arylphospholes 1a–c with phosphorus tribromide followed by treatment with morpholine afforded the 2- or 3-substituted species 3a,b or 7 (which after oxidation gave 4a,b or 8) in a selective manner.

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Article information

DOI
https://doi.org/10.1039/B002042G
Article type
Communication
Submitted
14 Mar 2000
Accepted
04 Apr 2000
First published
03 May 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 1495-1496

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A new reaction of arylphospholes: site-selective phosphorylation through reaction with phosphorus tribromide

G. Keglevich, T. Chuluunbaatar, A. Dobó and L. Tőke, J. Chem. Soc., Perkin Trans. 1, 2000, 1495 DOI: 10.1039/B002042G

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