Issue 11, 2000
From the journal:

New Journal of Chemistry

Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

Nicholas C. Norman,*a   A. Guy Orpen,a   Michael J. Quaylea  and  Craig R. Ricea  

* Corresponding authors

a School of Chemistry, Uniersity of Bristol, Cantock's Close, Bristol, UK
E-mail: N.C.Norman@Bristol.ac.uk

Abstract

The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2−, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2−.

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Article information

DOI
https://doi.org/10.1039/B004942P
Article type
Letter
Submitted
19 Jun 2000
Accepted
29 Aug 2000
First published
23 Oct 2000

New J. Chem., 2000,24, 837-839

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Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

N. C. Norman, A. Guy Orpen, M. J. Quayle and C. R. Rice, New J. Chem., 2000, 24, 837 DOI: 10.1039/B004942P

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