Racemic mixtures 1a–f, 2a–e crystallise as conglomerates at room temperature and lead to spontaneous resolution; tosylimines 1e and 2c give homochiral crystals (space group P1), whereas similar benzenesulfonyloximes 3a,b give heterochiral packings (space groups P21/n and P21/c, respectively).
R. G. Kostyanovsky, A. P. Avdeenko, S. A. Konovalova, G. K. Kadorkina and A. V. Prosyanik, Mendeleev Commun., 2000, 10, 16 DOI: 10.1070/MC2000v010n01ABEH001208
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