Issue 1, 2000

Synthesis, molecular and crystal structure of a tricarbonylchromium complex of 7-(2-phenyl-o-carboran-1-yl)cyclohepta-1,3,5-triene

Abstract

The reaction of substituted 1-lithio-o-carboranes with tropylium tetrafluoroborate produces 7-(o-carboran-1-yl)cyclohepta-1,3,5-trienes, which can also be obtained by decomplexation of the corresponding tricarbonylchromium complexes prepared from 1-lithio-o-carboranes and [(C7H7)Cr(CO)3]+BF4–.

Article information

Article type
Paper

Mendeleev Commun., 2000,10, 15-16

Synthesis, molecular and crystal structure of a tricarbonylchromium complex of 7-(2-phenyl-o-carboran-1-yl)cyclohepta-1,3,5-triene

V. N. Kalinin, I. V. Shishkov, S. K. Moiseev, P. V. Petrovskii, Z. A. Starikova and D. D. Sung, Mendeleev Commun., 2000, 10, 15 DOI: 10.1070/MC2000v010n01ABEH001184

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