Efficient reduction catalysis of viologen-bound iron porphyrin and its application to six-electron reduction of nitrobenzene to aniline

Shigeyoshi Sakaki; Hiroaki Koga; Kou-ichiro Tao; Takafumi Yamashita; Tetsuro Iwashita; Taisuke Hamada

doi:10.1039/B000146P

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Efficient reduction catalysis of viologen-bound iron porphyrin and its application to six-electron reduction of nitrobenzene to aniline†

Shigeyoshi Sakaki,*^a Hiroaki Koga,^a Kou-ichiro Tao,^a Takafumi Yamashita,^a Tetsuro Iwashita^a and Taisuke Hamada^a

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^a Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University, Kurokami, Kumamoto, Japan

Abstract

A newly synthesized methylviologen-bound iron porphyrin chloro(5-{4-[3-(1′-methyl-4,4′-bipyridinium)ethylcarboxyamidyl]phenyl}-10,15,20-triphenylporphyrin)iron dichloride, efficiently catalyzes six-electron reduction of nitrobenzene to aniline, a model reaction of NO₂⁻ conversion to NH₄⁺ by nitrite reductase.

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Supplementary files

Synthesis and characterisation of complex 1 and details of the oxygen addition technique used DOC (28K)

Article information

DOI: https://doi.org/10.1039/B000146P
Article type: Communication
Submitted: 10 Jan 2000
Accepted: 16 Feb 2000
First published: 09 Mar 2000

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J. Chem. Soc., Dalton Trans., 2000, 1015-1017

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Efficient reduction catalysis of viologen-bound iron porphyrin and its application to six-electron reduction of nitrobenzene to aniline

S. Sakaki, H. Koga, K. Tao, T. Yamashita, T. Iwashita and T. Hamada, J. Chem. Soc., Dalton Trans., 2000, 1015 DOI: 10.1039/B000146P

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Journal of the Chemical Society, Dalton Transactions

Efficient reduction catalysis of viologen-bound iron porphyrin and its application to six-electron reduction of nitrobenzene to aniline†

Abstract

Supplementary files

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Efficient reduction catalysis of viologen-bound iron porphyrin and its application to six-electron reduction of nitrobenzene to aniline

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