Inner C-arylation of a doubly N-confused porphyrin–Pd complex in toluene—the possibility of a Pd3+ intermediate

Hiroyuki Furuta; Hiromitsu Maeda; Atsuhiro Osuka; Mikio Yasutake; Teruo Shinmyozu; Yuichi Ishikawa

doi:10.1039/B003022H

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Inner C-arylation of a doubly N-confused porphyrin–Pd complex in toluene—the possibility of a Pd³⁺ intermediateElectronic supplementary information (ESI) available: synthesis details, ¹H and ¹³C NMR spectra, thermal ellipsoid plot showing all atoms, unit cell packing diagram for 2. See http://www.rsc.org/suppdata/cc/b0/b003022h/

Hiroyuki Furuta,*^a Hiromitsu Maeda,^a Atsuhiro Osuka,*^a Mikio Yasutake,^c Teruo Shinmyozu^c and Yuichi Ishikawa^c

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto, Japan.
E-mail: hfuruta@kuchem.kyoto-u-ac.jp, osuka@kuchem-kyoto-u.ac.jp

^b PRESTO, Japan Science of Technology Corporation (JST), Japan

^c Institute for Fundamental Research of Organic Chemistry, Kyushu University, Fukuoka, Japan

Abstract

An inner C-tolyl substituted Pd²⁺ complex of a doubly N-confused porphyrin (N₂CP) was obtained from the reaction of N₂CP and Pd(OAc)₂ in toluene and the structure was revealed by a single crystal X-ray analysis.

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Article information

DOI: https://doi.org/10.1039/B003022H
Article type: Communication
Submitted: 14 Apr 2000
Accepted: 18 May 2000
First published: 12 Jun 2000

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Chem. Commun., 2000, 1143-1144

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Inner C-arylation of a doubly N-confused porphyrin–Pd complex in toluene—the possibility of a Pd³⁺ intermediate

H. Furuta, H. Maeda, A. Osuka, M. Yasutake, T. Shinmyozu and Y. Ishikawa, Chem. Commun., 2000, 1143 DOI: 10.1039/B003022H

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