Synthesis of enantiopure isoprene epoxides from (S)-lactic acid via ‘dispoke’ intermediates

Daping Zhang; Christine Bleasdale; Bernard T. Golding; William P. Watson

doi:10.1039/B002133O

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Synthesis of enantiopure isoprene epoxides from (S)-lactic acidvia ‘dispoke’ intermediates

Daping Zhang,^a Christine Bleasdale,^a Bernard T. Golding*^a and William P. Watson †^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Newcastle upon Tyne, Bedson Building, Newcastle upon Tyne, UK
E-mail: b.t.golding@ncl.ac.uk

^b Shell International Chemicals BV, Shell Research and Technology Centre Amsterdam, Toxicology Department, PO Box 38000, Amsterdam, The Netherlands

Abstract

‘Dispoke protected lactate’ derived from (S)-lactic acid was converted into the enantiopure isoprene epoxides (S)-2-ethenyl-2-methyloxirane and (2R,2′S)-2-methylbioxirane.

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Article information

DOI: https://doi.org/10.1039/B002133O
Article type: Communication
Submitted: 14 Mar 2000
Accepted: 09 May 2000
First published: 12 Jun 2000

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Chem. Commun., 2000, 1141-1142

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Synthesis of enantiopure isoprene epoxides from (S)-lactic acid via ‘dispoke’ intermediates

D. Zhang, C. Bleasdale, B. T. Golding and W. P. Watson, Chem. Commun., 2000, 1141 DOI: 10.1039/B002133O

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