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Issue 1, 2000
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Total spontaneous resolution of a cyanoguanidine showing only conformational chirality

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Abstract

The total spontaneous resolution of N-(4-chlorophenyl)-N′-cyano-N,N″ ,N″-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.

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Submitted
16 Sep 1999
Accepted
23 Nov 1999
First published
06 Jan 2000

Chem. Commun., 2000, 61-62
Article type
Communication

Total spontaneous resolution of a cyanoguanidine showing only conformational chirality

I. D. Cunningham, S. J. Coles and M. B. Hursthouse, Chem. Commun., 2000, 61
DOI: 10.1039/A907518F

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