Issue 6, 1999

The molecular structure and the puckering potential function of octamethylcyclotetrasilane, Si4Me8, determined by gas electron diffraction and ab initio calculations

Abstract

The structural parameters, the barrier of inversion and the equilibrium puckering angle of Si4Me8 were determined using a dynamic model (V0 = 1.0±0.5 kcal mol–1, ϕe = 28.3±1.9°).

Article information

Article type
Paper

Mendeleev Commun., 1999,9, 217-219

The molecular structure and the puckering potential function of octamethylcyclotetrasilane, Si4Me8, determined by gas electron diffraction and ab initio calculations

V. P. Novikov, S. A. Tarasenko, S. Samdal and L. V. Vilkov, Mendeleev Commun., 1999, 9, 217 DOI: 10.1070/MC1999v009n06ABEH001170

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